Energy Exchange

Two chemicals that remind us why we should exercise caution with the oil industry’s wastewater

By Cloelle Danforth / Published: October 14, 2020

Over the past few years, we’ve written a lot about the wastewater generated from oil and gas production — specifically, how little is known about what’s in it and the potential risks of exposure.

But as states try to set standards for how to safely treat and dispose of this waste, there are two chemicals in particular that deserve to be among the regulatory priorities.

The first is a class of synthetic chemicals known as per- and polyfluoroalkyl substances — PFAS for short. Members of this class, often referred to as “forever chemicals” because they are highly persistent in the environment, are known to cause adverse health impacts in humans. This can include a range of symptoms, including damage to the immune system, low infant birth weights and cancer.

The second chemical is 1,4-dioxane. Short-term exposure to this carcinogen can cause immediate health impacts, like eye, nose and throat irritation and impaired lung function. Prolonged exposure can lead to liver and kidney damage, as well as cancer.

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Shining new light on the toxicity of chemicals in produced water

By Cloelle Danforth / Published: November 13, 2019

In the United States, onshore oil and gas extraction operations generate nearly a trillion gallons of produced water annually. It is the largest waste stream associated with upstream development of petroleum hydrocarbons.

As EDF has written in numerous posts, this wastewater from oil and gas wells can be complex and toxic. In addition to the chemicals companies use during drilling and extraction, it can contain a wide range of potentially harmful material that already existed in the ground, and can be many times saltier than seawater. There’s a lot of it, too. Some wells produce up to 10 times as much wastewater as they do oil.

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Could wastewater from oil and gas production help solve our water crisis? Not without better science

By Cloelle Danforth / Published: March 15, 2018

Climate change is drastically raising demands on the world’s fresh water supplies, and as a result, governments, scientists, and others are actively searching for new ways to manage and preserve our water resources.

One consideration includes repurposing wastewater generated from on-shore oil and gas development, which produces a whopping 900 billion gallons of water annually in the U.S. alone.

Some proponents of this option believe produced water may be a massive opportunity for water-scarce regions. Researchers at the University of Texas suggest recycling produced water for hydraulic fracturing operations could help address anticipated water shortage problems in the Permian Basin. Recycling wastewater within the oilfield is a viable option – as long as the spill and leaks, which can have significant and long-lasting negative impacts on soil and water resources, are minimized.

However, uses beyond the oilfield are much riskier if we don’t answer some critical questions first.

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New study reveals gaps in the methods used to assess chemicals in oilfield wastewater

By Cloelle Danforth / Published: August 28, 2017

A new study led by researchers with Colorado School of Mines exposes limitations with the current methods used to detect chemicals in oilfield wastewater and offers solutions to help regulators make better decisions for managing this waste stream.

Oilfield wastewater is extremely salty and can contain multiple combinations of many potentially harmful chemicals (approximately 1600 on a national basis). However, most standard or approved analytical methods available to regulators were designed to work with fresh water. Because oil and gas wastewater is so salty—sometimes 10 times saltier than seawater or more—chemists often have to dilute wastewater samples to manage the high salt content.

This means they may also be diluting chemicals of concern to concentrations too low to detect, even though they may be present at risky levels. For example, benzene is a chemical associated with petroleum hydrocarbons and a known carcinogen. It also has a drinking water standard of 5 parts per billion – that’s 5 cents in 10 million dollars. It really doesn’t take much dilution of a sample to lose that level of precision. Read More »

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What We Know – And Don’t Know – About Toxic Wastewater From The Oil And Gas Industry

By Cloelle Danforth / Published: June 21, 2016

By Cloelle Danforth and Steve Hamburg

For all that we hear and think about oil and gas production, wastewater may not be at the top of our list of concerns. And yet, onshore oil and gas operations in the United States produce more than 800 billion gallons of toxic wastewater each year.

Most oil and gas companies either dispose of this water deep underground, or recycle it for use in other wells. But a growing number of operators are now considering alternate ways to discharge or reuse this water above ground.

Before we can effectively manage this influx of wastewater in new ways, we need to have a better understanding of what’s in it. Read More »

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