{"id":3009,"date":"2014-01-30T17:38:04","date_gmt":"2014-01-30T22:38:04","guid":{"rendered":"http:\/\/blogs.edf.org\/health\/?p=3009"},"modified":"2024-02-12T11:01:33","modified_gmt":"2024-02-12T16:01:33","slug":"should-we-be-holding-our-breath-waiting-for-more-information-on-risks-of-the-chemical-spilled-in-west-virginia","status":"publish","type":"post","link":"https:\/\/blogs.edf.org\/health\/2014\/01\/30\/should-we-be-holding-our-breath-waiting-for-more-information-on-risks-of-the-chemical-spilled-in-west-virginia\/","title":{"rendered":"Should we be holding our breath waiting for more information on risks of the chemical spilled in West Virginia?"},"content":{"rendered":"<p><em>Richard Denison, Ph.D.<\/em><em>,<\/em> is a Senior Scientist.<\/p>\n<p><span style=\"color: #000000;font-family: Calibri;font-size: medium\">A <\/span><a href=\"http:\/\/www.legis.state.wv.us\/legisdocs\/2014\/committee\/interim\/water\/water_201401301504.pdf\"><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">hearing held yesterday<\/span><\/a><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"><span style=\"color: #000000\"> by the West Virginia Legislature\u2019s<\/span> <\/span><\/span><a href=\"http:\/\/www.legis.state.wv.us\/committees\/interims\/committee.cfm?abb=water\"><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">Joint Legislative Oversight Commission on State Water Resources<\/span><\/a><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"> <span style=\"color: #000000\">created quite a stir, when a witness \u2013<\/span> <span style=\"color: #000000\">West Virginia Environmental Quality Board vice-chairman Scott Simonton \u2013 said that the human carcinogen formaldehyde had been detected in several water samples drawn from a Charleston, WV, restaurant, and that people in the area affected by the January 9 spill could be expected to have inhaled the chemical, which he identified as a likely breakdown product of the spilled material, crude MCHM.\u00a0 See stories in the <\/span><\/span><\/span><a href=\"http:\/\/www.wvgazette.com\/News\/201401290053\"><i><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">Charleston Gazette<\/span><\/i><\/a><span style=\"color: #000000;font-family: Calibri;font-size: medium\"> and <\/span><a href=\"http:\/\/www.usatoday.com\/story\/news\/nation\/2014\/01\/29\/freedom-industries-spill-formaldehyde\/5031963\/\"><i><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">USA Today<\/span><\/i><\/a><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"><span style=\"color: #000000\">.<\/span><\/span><\/span><\/p>\n<p><a href=\"http:\/\/www.wvdhhr.org\/presentationUnfounded12914.pdf\"><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">State officials<\/span><\/a><span style=\"color: #000000;font-family: Calibri;font-size: medium\"> and the <\/span><a href=\"http:\/\/files.shareholder.com\/downloads\/AMERPR\/2930024215x0x721849\/02fb002b-813e-4333-a2f7-94c3dd364342\/WVAW_Response_to_Reports_Regarding_Formaldehyde.pdf\"><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">West Virginia American Water<\/span><\/a><span style=\"color: #000000;font-family: Calibri;font-size: medium\"> company were quick to call Simonton\u2019s claims \u201cunfounded\u201d and \u201cmisleading and irresponsible,\u201d respectively.\u00a0 The controversy led even the American Chemistry Council \u2013 which has laid low ever since the spill \u2013 to quickly issue its first statement related to the spill\u00a0<\/span><a href=\"http:\/\/www.americanchemistry.com\/Media\/PressReleasesTranscripts\/ACC-news-releases\/Formaldehyde-Is-Biodegradable.html\"><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">through its Formaldehyde Panel<\/span><\/a><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"><span style=\"color: #000000\">.<\/span><\/span><\/span><\/p>\n<p><span style=\"font-size: medium\"><span style=\"color: #000000\"><span style=\"font-family: Calibri\">While experts are noting that data are insufficient to identify the spill as the source of any formaldehyde detected in the water samples, this new kerfuffle does point to yet another major data gap on crude MCHM.<\/span><\/span><\/span><\/p>\n<p><span style=\"color: #000000\"><span style=\"font-size: medium\"><span style=\"font-family: Calibri\">The one part-per-million (1 ppm) \u201csafe\u201d level state and federal officials set was based on limited data from studies in which rats were exposed to crude or pure MCHM through <i>oral ingestion<\/i>.\u00a0 <\/span><\/span><\/span><a href=\"http:\/\/emergency.cdc.gov\/chemical\/MCHM\/westvirginia2014\/pdf\/MCHM-Summary-Report.pdf\"><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">Absolutely no data are available<\/span><\/a><span style=\"color: #000000;font-family: Calibri;font-size: medium\"> on the chemical with respect to exposure through <i>inhalation<\/i>.\u00a0 Yet <\/span><a href=\"http:\/\/emergency.cdc.gov\/chemical\/MCHM\/westvirginia2014\/index.asp\"><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">officials did not hesitate to tell residents<\/span><\/a><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"><span style=\"color: #000000\"> the 1 ppm level would be safe not only for drinking the water, but also for bathing and showering.<\/span><\/span><\/span><\/p>\n<p><span style=\"color: #000000;font-family: Calibri;font-size: medium\">(It\u2019s curious that the Eastman Chemical Company apparently performed no inhalation studies on crude or pure MCHM, <\/span><a href=\"http:\/\/www.eastman.com\/literature_center\/misc\/Q_and_A_West_Virginia_Spill.pdf\"><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">given that Eastman said its motivation for the studies<\/span><\/a><span style=\"color: #000000;font-family: Calibri;font-size: medium\"> it did perform was to understand risks to workers in industrial settings, and its <\/span><a href=\"http:\/\/ws.eastman.com\/ProductCatalogApps\/PageControllers\/MSDS_PC.aspx?Product=71014291\"><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">safety data sheet for crude MCHM<\/span><\/a><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"><span style=\"color: #000000\"> prominently notes the potential for health concerns for workers from inhalation.)<\/span><\/span><\/span><\/p>\n<p><em><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"><span style=\"color: #000000\">[UPDATE 1\/31\/14:\u00a0 This morning, Eastman posted an updated version of its Q&amp;A document on its website (linked to in the above paragraph), and took down the earlier version.\u00a0 Here is the <a href=\"https:\/\/blogs.edf.org\/health\/wp-content\/blogs.dir\/11\/files\/2014\/01\/Eastman-Q_and_A_West_Virginia_Spill.pdf\">original version<\/a>, the <a href=\"https:\/\/blogs.edf.org\/health\/wp-content\/blogs.dir\/11\/files\/2014\/01\/Eastman-Q_and_A_West_Virginia_Spill-Updated-version-1-31-14.pdf\">updated version dated 1\/31\/14<\/a>, and a <a href=\"https:\/\/blogs.edf.org\/health\/wp-content\/blogs.dir\/11\/files\/2014\/01\/Comparison-of-two-versions-of-Eastmans-Questions-and-Answers-Regarding-WV-spill.docx\">redline comparison of the two versions<\/a>.]<\/span><\/span><\/span><\/em><\/p>\n<p><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"><span style=\"color: #000000\">Clearly the material that spilled is volatile \u2013 that\u2019s why people can smell it.\u00a0 Taking a hot shower in such water means that people would clearly be exposed via inhalation of the vapor; how much exposure would occur has not been ascertained.\u00a0 But in the absence of any data as to toxicity of the chemical via inhalation, there is simply no scientific basis on which to say or imply that showering in water contaminated at 1 ppm level was OK.<\/span><\/span><\/span><\/p>\n<p><span style=\"color: #000000;font-family: Calibri;font-size: medium\">Chemicals can be more or less toxic by inhalation than by ingestion, with <\/span><a href=\"http:\/\/www.ncbi.nlm.nih.gov\/pubmed\/14746775\"><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">one study<\/span><\/a><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"><span style=\"color: #000000\"> finding inhalation to be the more toxic route for half of the chemicals examined and oral ingestion to be the more toxic route for the other half.\u00a0 Benzene, for example, is estimated to be several hundred times more toxic by inhalation than by ingestion, while inhalation of chloroform is estimated to be about 25-fold lower in toxicity than it is by ingestion. <\/span><\/span><\/span><\/p>\n<p><span style=\"font-size: medium\"><span style=\"color: #000000\"><span style=\"font-family: Calibri\">What such comparisons indicate is that extrapolating from data on oral toxicity to predict inhalation toxicity \u2013 which is effectively what government officials did in this case \u2013 is about as accurate as flipping a coin.<\/span><\/span><\/span><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Richard Denison, Ph.D., is a Senior Scientist. A hearing held yesterday by the West Virginia Legislature\u2019s Joint Legislative Oversight Commission on State Water Resources created quite a stir, when a witness \u2013 West Virginia Environmental Quality Board vice-chairman Scott Simonton \u2013 said that the human carcinogen formaldehyde had been detected in several water samples drawn &#8230;<\/p>\n","protected":false},"author":100,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[75,44,5009],"tags":[39150,39171,39164,39996],"coauthors":[],"class_list":["post-3009","post","type-post","status-publish","format-standard","hentry","category-environment","category-policy","category-health-science","tag-american-chemistry-council","tag-exposure-vs-hazard","tag-formaldehyde","tag-wv-chemical-spill"],"acf":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/posts\/3009","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/users\/100"}],"replies":[{"embeddable":true,"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/comments?post=3009"}],"version-history":[{"count":1,"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/posts\/3009\/revisions"}],"predecessor-version":[{"id":12699,"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/posts\/3009\/revisions\/12699"}],"wp:attachment":[{"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/media?parent=3009"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/categories?post=3009"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/tags?post=3009"},{"taxonomy":"author","embeddable":true,"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/coauthors?post=3009"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}