{"id":2974,"date":"2014-01-22T12:45:44","date_gmt":"2014-01-22T17:45:44","guid":{"rendered":"http:\/\/blogs.edf.org\/health\/?p=2974"},"modified":"2024-02-12T11:01:33","modified_gmt":"2024-02-12T16:01:33","slug":"another-new-wrinkle-on-the-new-mystery-chemical-in-west-virginia-spill","status":"publish","type":"post","link":"https:\/\/blogs.edf.org\/health\/2014\/01\/22\/another-new-wrinkle-on-the-new-mystery-chemical-in-west-virginia-spill\/","title":{"rendered":"Another new wrinkle on the \u201cnew\u201d mystery chemical in West Virginia spill"},"content":{"rendered":"<p><em>Richard Denison, Ph.D.<\/em><em>,<\/em> is a Senior Scientist.<\/p>\n<p><span style=\"color: #000000;font-family: Calibri;font-size: medium\">Well, this story is rapidly evolving!\u00a0 Even since my <\/span><a href=\"https:\/\/blogs.edf.org\/health\/2014\/01\/22\/is-this-the-mystery-chemical-in-the-wv-spill\/\"><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">last blog post<\/span><\/a><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"><span style=\"color: #000000\"> this morning, new information has come to light as to the identity of the \u201cnew\u201d chemical that was present in the leaking tank that led to contamination of the drinking water in Charleston, WV.<\/span><\/span><\/span><\/p>\n<p><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"><span style=\"color: #000000\">The <\/span><i><a href=\"http:\/\/www.wvgazette.com\/News\/201401220031\"><span style=\"color: #0000ff\">Charleston Gazette has now reported<\/span><\/a><\/i><span style=\"color: #000000\"> that Freedom Industries, the owner of the leaking tank, has told government officials that the \u201cnew\u201d chemical is actually a mixture of two chemical products, both of them made by The Dow Chemical Company.\u00a0 One of those is in fact the \u201c<\/span><\/span><a href=\"https:\/\/blogs.edf.org\/health\/wp-content\/blogs.dir\/11\/files\/2014\/01\/Glycol-Ether-2-PPH.pdf\"><span style=\"color: #0000ff\"><span style=\"font-size: medium\">DOWANOL<\/span><sup><span style=\"font-size: small\">TM<\/span><\/sup><span style=\"font-size: medium\"> PPh Glycol Ether<\/span><\/span><\/a><span style=\"color: #000000;font-size: medium\">\u201d I discussed in my last post.\u00a0 The second is a closely related Dow product called \u201c<\/span><a href=\"https:\/\/blogs.edf.org\/health\/wp-content\/blogs.dir\/11\/files\/2014\/01\/Glycol-Ether-1-DiPPH.pdf\"><span style=\"color: #0000ff\"><span style=\"font-size: medium\">DOWANOL<\/span><sup><span style=\"font-size: small\">TM<\/span><\/sup><span style=\"font-size: medium\"> DiPPh Glycol Ether<\/span><\/span><\/a><span style=\"font-size: medium\"><span style=\"color: #000000\">.\u201d \u00a0\u00a0(These links are to Dow\u2019s Material Safety Data Sheets (MSDSs) for the two products.)<\/span><\/span><\/span><\/p>\n<p><span style=\"color: #000000;font-family: Calibri;font-size: medium\">The first product consists almost entirely (&gt;99.5%) of <\/span><a href=\"http:\/\/chem.sis.nlm.nih.gov\/chemidplus\/rn\/770-35-4\"><span style=\"color: #0000ff\"><span style=\"font-size: medium\"><span style=\"font-family: Calibri\">propylene glycol phenyl ether (CAS no. 770-35-4)<\/span><\/span><\/span><\/a><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"><span style=\"color: #000000\">.\u00a0 The second is a mixture (see its MSDS), the main component of which (\u226560%) is <\/span><i><a href=\"http:\/\/chem.sis.nlm.nih.gov\/chemidplus\/rn\/51730-94-0\"><span style=\"color: #0000ff\">di-<\/span><\/a><\/i><a href=\"http:\/\/chem.sis.nlm.nih.gov\/chemidplus\/rn\/51730-94-0\"><span style=\"color: #0000ff\">propylene glycol phenyl ether (CAS no. 51730-94-0)<\/span><\/a><span style=\"color: #000000\"> \u2013 a closely related chemical.<\/span><\/span><\/span><\/p>\n<p><span style=\"color: #000000;font-family: Calibri;font-size: medium\">My earlier post indicated that a Dow contact had told me this morning it does not make a \u201cstripped\u201d version of its PPh product, and hence did not believe it was the supplier of the material to Freedom Industries.\u00a0 As I noted in that post, use of the \u201cstripped\u201d designation to describe the \u201cproprietary\u201d chemical listed in the <\/span><a href=\"https:\/\/blogs.edf.org\/health\/wp-content\/blogs.dir\/11\/files\/2014\/01\/MSDS-for-PPH.pdf\"><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">MSDS supplied yesterday by Freedom Industries<\/span><\/a><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"><span style=\"color: #000000\"> for the \u201cnew\u201d chemical had suggested the substance had somehow been further distilled.<\/span><\/span><\/span><\/p>\n<p><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"><span style=\"color: #000000\">But the latest article in the <\/span><i><a href=\"http:\/\/www.wvgazette.com\/News\/201401220031\"><span style=\"color: #0000ff\">Charleston Gazette<\/span><\/a><\/i><span style=\"color: #000000\"> helps to clarify the situation.\u00a0 It cites State officials indicating that Freedom Industries\u2019 \u201cPPH, stripped\u201d is in fact a mixture of the two Dow products.<\/span><\/span><\/span><\/p>\n<p><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"><span style=\"color: #000000\">Interestingly, the MSDSs for the two Dow products reference a considerably larger amount of toxicity data than does Freedom Industries\u2019 MSDS.\u00a0 It appears, therefore, that there may be more data for officials to go on to assess potential risks associated with this \u201cnew\u201d chemical.<\/span><\/span><\/span><\/p>\n<p><span style=\"color: #000000;font-family: Calibri;font-size: medium\">Dow\u2019s <\/span><a href=\"http:\/\/msdssearch.dow.com\/PublishedLiteratureDOWCOM\/dh_08ad\/0901b803808ad688.pdf?filepath=oxysolvents\/pdfs\/noreg\/110-00622.pdf&amp;fromPage=GetDoc\"><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">Technical Data Sheet<\/span><\/a><span style=\"color: #000000;font-family: Calibri;font-size: medium\"> and <\/span><a href=\"http:\/\/msdssearch.dow.com\/PublishedLiteratureDOWCOM\/dh_0119\/0901b80380119ff3.pdf?filepath=productsafety\/pdfs\/noreg\/233-00405.pdf&amp;fromPage=GetDoc\"><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">Product Safety Assessment<\/span><\/a><span style=\"color: #000000;font-family: Calibri;font-size: medium\"> for <\/span><span style=\"font-family: Calibri\"><span style=\"color: #000000\"><span style=\"font-size: medium\">\u201c<\/span><span style=\"font-size: medium\">DOWANOL<\/span><sup><span style=\"font-size: small\">TM<\/span><\/sup><span style=\"font-size: medium\"> PPh Glycol Ether\u201d list several uses for the product, none of which appear to explain why Freedom Industries would have added the product to the tank of MCHM, which is used to wash coal.<\/span><\/span><\/span><\/p>\n<p><span style=\"color: #000000;font-family: Calibri;font-size: medium\">There appear to be some disconnects between Dow\u2019s knowledge of how its own chemicals are being used and by whom, and also between the intended uses of such chemicals and their actual use.\u00a0 These disconnects point to <\/span><a href=\"http:\/\/www.edf.org\/health\/policy\/chemicals-policy-reform\"><span style=\"color: #0000ff;font-family: Calibri;font-size: medium\">flaws in our current chemical safety policies<\/span><\/a><span style=\"font-family: Calibri\"><span style=\"font-size: medium\"><span style=\"color: #000000\">:\u00a0 chemical manufacturers often don\u2019t have a full picture of how their chemicals are actually used, and downstream users may not have a clear picture of which uses of a chemical are appropriate or not.<\/span><\/span><\/span><\/p>\n<p><span style=\"font-size: medium\"><span style=\"color: #000000\"><span style=\"font-family: Calibri\">The number of lessons to be drawn from this West Virginia chemical spill appears to be growing by the day.<\/span><\/span><\/span><\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Richard Denison, Ph.D., is a Senior Scientist. Well, this story is rapidly evolving!\u00a0 Even since my last blog post this morning, new information has come to light as to the identity of the \u201cnew\u201d chemical that was present in the leaking tank that led to contamination of the drinking water in Charleston, WV. The Charleston &#8230;<\/p>\n","protected":false},"author":100,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[75,44,56096],"tags":[39155,39171,39993,39996],"coauthors":[],"class_list":["post-2974","post","type-post","status-publish","format-standard","hentry","category-environment","category-policy","category-omboira","tag-cbi","tag-exposure-vs-hazard","tag-general-interest","tag-wv-chemical-spill"],"acf":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/posts\/2974","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/users\/100"}],"replies":[{"embeddable":true,"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/comments?post=2974"}],"version-history":[{"count":1,"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/posts\/2974\/revisions"}],"predecessor-version":[{"id":12697,"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/posts\/2974\/revisions\/12697"}],"wp:attachment":[{"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/media?parent=2974"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/categories?post=2974"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/tags?post=2974"},{"taxonomy":"author","embeddable":true,"href":"https:\/\/blogs.edf.org\/health\/wp-json\/wp\/v2\/coauthors?post=2974"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}